You can always add another item to the loot drop id and set it to whatever percentage you want so it drops in place of the defiant armor. For example, you could put a cloth cap with 90% chance of dropping in a 1% chance loot drop id, then have 10 defiant items set each to 1%. That would effectively make the cloth cap a 0.9% chance to drop and the defiant gear would be 0.1% chance or 1 in 1000 for any one of the 10 pieces to drop. That would make each defiant piece 0.01% or 1 in 10,000 chance to drop.
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